@Article{BaranauskasCLPTCSL:2000:DiCoPo,
author = "Baranauskas, V. and Chang, D. C. and Li, B. B. and Peterlevitz, A.
C. and Trava-Airoldi, Vladimir Jesus and Corat, Evaldo Jose and
Singh, R. K. and Lee, D. G.",
affiliation = "Baranauskas V (reprint author), Univ Estadual Campinas, Fac Engn
Eletr \& Comp, Av Albert Einstein,N400, Campinas, SP BR-13083970
Brazil and Univ Estadual Campinas, Fac Engn Eletr \& Comp,
Campinas, SP BR-13083970 Brazil and Inst Nacl Pesquisas Espaciais,
Lab Associado Sensores \& Mat, Sao Jose Dos Campos, BR-12201
Brazil and Univ Florida, Dept Mat Sci \& Engn, Gainesville, FL
32611 USA",
title = "Diamond coating of porous silicon",
journal = "Journal of Porous Materials",
year = "2000",
volume = "7",
number = "1-3",
pages = "401--404",
month = "Jan.",
keywords = "porous silicon coating, diamond on porous silicon, diamond
nucleation.",
abstract = "Diamond coatings on porous silicon (PS) samples have been obtained
by the hot-filament chemical vapor deposition(CVD) technique. We
focused our attention on the coating morphology, showing
experimentally that high quality diamond coatings may be produced
with the PS sample kept at 710 degrees C. The deposited patterns
consist of polycrystalline grains with a plane interface with the
PS layer. At 790 degrees C, the quality of the coating is improved
but the PS layer becomes damaged, and at 650 degrees C the coating
consists of diamond-like carbon particles. Besides the
temperature, other factors such as the porosity, roughness and
chemical activity of the PS layer deserve attention. We observed
that one of the limiting factors of the deposition process was the
high nucleation time. Two nucleation mechanisms are involved in
the growth process. The first nucleation mechanism occurs on the
top of the sharp PS features, subsequently to the nucleation a
superficial film, and then a second nucleation mechanism occurs
over this surface, which allows the growth process to continue. We
also observed the presence of a blue-shift in the luminescence
spectra following the coating.",
copyholder = "SID/SCD",
issn = "1380-2224",
language = "en",
targetfile = "diamond coating.pdf",
urlaccessdate = "10 maio 2024"
}